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2005
Electrochemical reactions
M 7000
Development of Electrochemical Processes for Nitrene Generation and Transfer.
It is found that molecules which are similar in terms of propensity toward oxidation
25- 028 —
can be differentiated on the basis of their affinity to a given electrode surface. So, combination of Pt electrodes, NEt3, and AcOH allows simple and selective oxidation of the
amine (II) to a nitrene in the presence of various olefins and sulfoxides. The nitrene
smoothly reacts with olefins and sulfoxides to afford aziridines and sulfoximines (no
yields given). — (SIU, T.; PICARD, C. J.; YUDIN*, A. K.; J. Org. Chem. 70 (2005)
3, 932-937; Dep. Chem., Univ. Toronto, Toronto, Ont. M5S 3H6, Can.; Eng.) —
Jannicke
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