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2005
Indium
I 2300
26- 012
Na5(In 4S)(InS 4)3·6H2O, a Zeolite-Like Structure with Unusual SIn4 Tetrahedra.
— The structure of title compound (III) is determined by single crystal XRD (space
group F43c, Z = 8). A characteristic feature of the structure is the presence of a tetrahedral sulfur site coordinated to four trivalent indium ions, an unusual bonding pattern
not previously observed in open framework chalcogenides. (III) is a wide-gap semiconductor and shows photocatalytic activity for H2 generation from H2O under UV irradiation without use of any cocatalyst. — (ZHENG, N.; BU, X.; FENG*, P.; J. Am.
Chem. Soc. 127 (2005) 15, 5286-5287; Dep. Chem., Univ. Calif., Riverside,
CA 92521, USA; Eng.) — Schramke
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