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2005
Reduction
O 0220
26- 033
Use of CaH2 as a Reductive Hydride Source: Reduction of Ketones and Imines
with CaH2/ZnX2 in the Presence of a Lewis Acid. — A new combination reagent of
CaH2 and zinc halide is described to reduce various ketones and imines to the corresponding alcohols and imines. The reaction is efficiently promoted by catalytic
amounts of Lewis acid such as Ti(O-iPr)4. — (AIDA, T.; KUBOKI, N.; KATO, K.;
UCHIKAWA, W.; MATSUNO, C.; OKAMOTO*, S.; Tetrahedron Lett. 46 (2005) 10,
1667-1669; Dep. Appl. Chem., Fac. Eng., Kanagawa Univ., Kanagawa, Yokohama
221, Japan; Eng.) — Mais
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