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2005
Cyclohexane derivatives
Q 0040
The Boron-Mediated Ketone—Ketone Aldol Reaction. — Transformation of a
of ketones to their boron enolates and subsequent reaction with acceptor ketones
26- 046 variety
followed by oxidative work-up provides the first examples of a directed aldol reaction
between different ketones. The reaction works best with cyclic ketones and the highest
yields are obtained for cyclohexanone as the acceptor ketone. — (CERGOL, K. M.;
TURNER, P.; COSTER*, M. J.; Tetrahedron Lett. 46 (2005) 9, 1505-1509; Sch.
Chem., Univ. Sydney, Camperdown, N. S. W. 2006, Australia; Eng.) — Mais
2005
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