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2005
Structure
D 2000
27- 004
Synthesis and Crystal Structure of Na2LiAlD6. — The title compound is prepared
by ball milling of NaAlD4 and LiAlD 4 with subsequent heat treatment at 180 °C under
30 bar D2 pressure. Na2LiAlD6 crystallizes in the in the cubic space group Fm3m with
Z = 4, as revealed by powder neutron diffraction. The structure consists of a network
of corner-sharing AlD6 and LiD6 octahedra where each octahedron is surrounded by six
different octahedra. — (BRINKS*, H. W.; HAUBACK, B. C.; JENSEN, C. M.;
ZIDAN, R.; J. Alloys Compd. 392 (2005) 1-2, 27-30; Dep. Phys., Inst. Energ.
Technol., N-2027 Kjeller, Norway; Eng.) — W. Pewestorf
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