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2005
Silver
I 7500
27- 024
From AgCN Chains to a Fivefold Helix and a Fishnet-Shaped Framework Structure. — The structures of the new silver cyanide compounds (III), (V), and (VII) (yields
given in gram) are determined by single crystal XRD. (III) crystallizes in the tetragonal
space group I41/amd with Z = 4, (V) in the orthorhombic space group Fddd with Z = 8,
and compound (VII) in the cubic space group I43d with Z = 12. (III) exhibits a zeolitic
framework of cross-linked, rope-like twisted fivefold helices, compound (V) is a layered polymer knotted like a fishnet, and (VII) is a simple double salt. — (URBAN, V.;
PRETSCH, T.; HARTL*, H.; Angew. Chem., Int. Ed. 44 (2005) 18, 2794-2797; Inst.
Anorg. Anal. Chem., FU Berlin, D-14195 Berlin, Germany; Eng.) — W. Pewestorf
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