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2005
Reactions of organo-metal compounds
O 0350
Highly Alkyl-Selective Addition to Ketones with Magnesium Ate Complexes
from Grignard Reagents. — The title reactions with Grignard reagents and
27- 066 Derived
alkyllithiums is described. Remarkable improvements are observed with R3MgLi ate
complex systems. It is demonstrated that a highly selective addition to ketones takes
place using RMe2MgLi in place of R 3MgLi. 2,2'-Bipyridyl is shown to accelerate the
butylation of ketones. — (HATANO, M.; MATSUMURA, T.; ISHIHARA*, K.; Org.
Lett. 7 (2005) 4, 573-576; Grad. Sch. Eng., Nagoya Univ., Chikusa, Nagoya 464,
Japan; Eng.) — Steudel
2005
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