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2005
Reactions of organo-metal compounds
Reactions of organo-metal compounds
O 0350
New Synthetic Applications of Indium Organometallics in Cross-Coupling Reac— Di- and trihaloarenes including heterocyclic compounds are useful partners
28- 058 tions.
for triorganoindium reagents. Multifold cross-coupling reactions give the corresponding symmetrically alkylated or arylated products (multiple similar bonds are formed in
one step). They can be performed under a CO atmosphere affording di- or triacylbenzene derivatives in one pot. Sequential cross-coupling reactions provide unsymmetrically substituted products (multiple different bonds are formed in one pot). This latter
reaction illustrates the high chemoselectivity of the triorganoindium reagents. —
(PENA, M. A.; PEREZ SESTELO*, J.; SARANDESES, L. A.; Synthesis 2005, 3,
485-492; Dep. Quim. Fundam. Ind., Fac. Cienc., Univ. La Coruna, E-15071 La Coruna,
Spain; Eng.) — Klein
2005
Reactions of organo-metal compounds
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