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2005
Cyclohexane derivatives
Cyclohexane derivatives
Q 0040
1,2-Acyl Transfer Reaction for the Construction of Multiple Carbonyl-FunctionArchitecture by Sm(II)-Induced Tandem Formation and Breaking of Cy28- 068 alized
clopropanol. — The procedure offers an efficient approach to various 2-acyl-4-oxocarboxylates. However, some limitations are observed. The transfer proceeds with high
stereoselectivity and allows introduction of an acyl group onto a quaternary carbon center. — (INOKUCHI, T.; J. Org. Chem. 70 (2005) 4, 1497-1500; Dep. Biosci.
Biotechnol., Fac. Eng., Okayama Univ., Okayama 700, Japan; Eng.) — Jannicke
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