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2005
Amines
Q 0120
28- 074
Amines
Buchwald—Hartwig Aminations of Aryl Chlorides: A Practical Protocol Based
on Commercially Available Pd(0)-NHC Catalysts. — It is demonstrated that commercially available one-component complexes of type (I) and (II) are highly effective
for the Pd-catalyzed amination of aryl chlorides. Key advantages are the stability of the
complexes towards oxygen and water, the low catalyst loading and the use of cheap
bases such as KOH. — (GOOSSEN*, L. J.; PAETZOLD, J.; BRIEL, O.;
RIVAS-NASS, A.; KARCH, R.; KAYSER, B.; Synlett 2005, 2, 275-278; Inst. Org.
Chem., RWTH Aachen, D-52074 Aachen, Germany; Eng.) — Mais
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