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2005
Pyrrole derivatives
Pyrrole derivatives
R 0120
Diastereoselective Petasis Mannich Reactions Accelerated by HexafluoroisoproA Pyrrolidine-Derived Arylglycine Synthesis. — A diastereoselective syn28- 124 panol:
thesis of pyrrolidine-derived arylglycines is achieved via a Petasis boronic acid Mannich reaction. The use of hexafluoroisopropanol as a co-solvent dramatically reduces
the reaction times. The scope of this diastereoselective process with regard to boronic
acid and the amine component is established. — (NANDA*, K. K.; TROTTER, B. W.;
Tetrahedron Lett. 46 (2005) 12, 2025-2028; Dep. Med. Chem., Merck Res. Lab.,
West Point, PA 19486, USA; Eng.) — D. Singer
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