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2005
Enantioselective syntheses
O 0031
Kinetic Resolution of sec-Alcohols by a New Class of Pyridine Catalysts Having a
Switch System. — A class of chiral acylating catalysts (I) is described
29- 032 Conformation
having a conformation switch system induced by acylation and deacylation. The kinetic
resolution of various sec-alcohols is achieved with good stereoselectivities using isobutyric anhydride as acylating agent. — (YAMADA*, S.; MISONO, T.; IWAI, Y.;
Tetrahedron Lett. 46 (2005) 13, 2239-2242; Dep. Chem., Fac. Sci., Ochanomizu
Univ., Bunkyo, Tokyo 112, Japan; Eng.) — Mais
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