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2005
Cycloaddition reactions
O 0070
Low-Melting Sugar—Urea—Salt Mixtures as Solvents for Diels—Alder Reac— Use of low-melting mixtures of bulk natural products such as carbohydrates
29- 040 tions.
with dimethylurea and inorganic salts as reaction media for Diels—Alder reactions
allow for fast conversions with good endo-exo selectivity. However, no significant
stereoinduction on the course of the reaction is detected. — (IMPERATO, G.;
EIBLER, E.; NIEDERMAIER, J.; KOENIG*, B.; Chem. Commun. (Cambridge)
2005, 9, 1170-1172; Inst. Org. Chem., Univ. Regensburg, D-93053 Regensburg,
Germany; Eng.) — D. Singer
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