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2005
C-C bond formation
O 0282
Barbier-Type Reaction Mediated with Tin Nano-Particles in Water. — It is found
the reaction mediated by tin nanoparticles leads to better yields of homoallylic
29- 057 that
alcohols than the allylation using regular tin particles. The regio- and diastereoselectivity can also be improved. The reaction proceeds via formation of allyltin bromide
and diallyltin dibromide. — (ZHA, Z.; QIAO, S.; JIANG, J.; WANG, Y.; MIAO*, Q.;
WANG*, Z.; Tetrahedron 61 (2005) 9, 2521-2527; Dep. Chem., Univ. Sci. Technol.
China, Hefei 230026, Anhui, Peop. Rep. China; Eng.) — Jannicke
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