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2005
Alcohols
Q 0230
29- 089
Indium-Mediated Barbier-Type Allylation of Aldehydes as a Convenient Method
for the Highly Enantioselective Synthesis of Homoallylic Alcohols. — It is demonstrated that commercially available ADE is an effective chiral promoter in the allylation
of aldehydes (I). The enantioselectivities are the highest obtained for In-promoted allylation of carbonyl compounds. — (HIRAYAMA, L. C.; GAMSEY, S.; KNUEPPEL,
D.; STEINER, D.; DELATORRE, K.; SINGARAM*, B.; Tetrahedron Lett. 46 (2005)
13, 2315-2318; Dep. Chem. Biochem., Univ. Calif., Santa Cruz, CA 95064, USA;
Eng.) — Mais
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