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2005
Carboxylic amides
Q 0490
Addition of Carbamoylsilanes to Electrophilically Substituted Alkenes. Preparaof β-Functionalized Tertiary Amides. — The title reactions are investigated for
29- 097 tion
silanes (II) and (IV), where the latter are more reactive. β-Silyl-β-functionalized amides
are obtained as products of regiospecific addition to the carbon—carbon double bond.
If sterically hindered alkenic esters are used, addition to the carbon—oxygen double
bond is observed. — (CUNICO*, R. F.; MOTTA, A. R.; Org. Lett. 7 (2005) 5,
771-774; Dep. Chem. Biochem., North. Ill. Univ., DeKalb, IL 60115, USA; Eng.) —
Steudel
2005
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