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2005
Polyphenylalkane derivatives
Q 0720
Suzuki—Miyaura Cross-Coupling of Benzylic Carbonates with Arylboronic
— Benzylic carbonates are shown to be a new class of coupling partners in the
29- 104 Acids.
title reaction. In the presence of a palladium catalyst and bidentate bisphosphine, they
afford the products in excellent yields. The reaction tolerates a variety of functional
groups in both carbonate and arylboronic acids. Alkenyl- but not alkylboronic acids are
also successfully used in the reaction. — (KUWANO*, R.; YOKOGI, M.; Org. Lett.
7 (2005) 5, 945-947; Dep. Chem., Fac. Sci., Kyushu Univ., Higashi, Fukuoka 812,
Japan; Eng.) — Steudel
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