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2005
Optical properties
D 6000
Nonlinear Optical Crystal YxLayScz(BO3)4 (x + y + z = 4). — Large single crystals
approximate composition Y0.57La0.72 Sc2.71(BO3)4 are prepared from mixtures of Y2O3,
30- 014 of
La2O3, Sc2O3, B2O3, and Li2O using 3Li2O·2B2O3 as flux (1050 °C, 2 d). The compound
crystallizes in the trigonal space group R32 with Z = 3. Measurements of the optical
properties indicate a wide transparency range extending into the deep UV, a moderate
birefringence, and a high second-order susceptibility coefficient. These features make
the compound a promising nonlinear optical material for practical applications. —
(YE, N.; STONE-SUNDBERG, J. L.; HRUSCHKA, M. A.; AKA, G.; KONG, W.;
KESZLER*, D. A.; Chem. Mater. 17 (2005) 10, 2687-2692; Dep. Chem., Oreg. State
Univ., Corvallis, OR 97331, USA; Eng.) — W. Pewestorf
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