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2005
Silver
I 7500
30- 029
Silver-Hydrogen Interactions in Crystalline Silver Dodecahydrododecaborates.
— The syntheses and single crystal structures of the three silver dodecahydrododecaborates and two dodecabromododecaborates are presented. Compounds (III), (IV), and
(VI) crystallize in the monoclinic space group P21/c with Z = 4. The Ag + cations are
connected to the [B12H12]2- cages by single or double hydrogen bonds to give chains
(III), layers (IV), or a three-dimensional connection (VI), respectively. (VII) crystallizes in the triclinic space group P1 with Z = 1 and (IX) in the monoclinic space group
P21/c with Z = 2. — (VOLKOV, O.; HU, C.; PAETZOLD*, P.; Z. Anorg. Allg. Chem.
631 (2005) 6-7, 1107-1112; Inst. Anorg. Chem., RWTH Aachen, D-52074 Aachen,
Germany; Eng.) — Schramke
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