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2005
Halogen compounds
Q 0090
A Bimetallic Ruthenium Ethylene Complex as a Catalyst Precursor for the
Reaction. — RUCEt, obtained in a one-step procedure from commercially
30- 062 Kharasch
available starting materials, is used for the catalysis of radical addition of CCl4 and
CHCl3 to olefins. The results show that the new catalyst is one of the most active ones.
For addition reactions with the less reactive substrate CHCl3, higher catalyst concentrations and elevated temperature are required. — (QUEBATTE, L.; SOLARI, E.;
SCOPELLITI, R.; SEVERIN*, K.; Organometallics 24 (2005) 7, 1404-1406; Inst.
Sci. Ing. Chim., Ec. Polytech. Fed. Lausanne, CH-1015 Lausanne, Switz.; Eng.) —
S. Adam
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