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2005
Electrochemical reactions
M 7000
Development of an Electrolytic System Using Solid-Supported Bases for in situ
of a Supporting Electrolyte from Methanol as a Solvent. — Anodic
31- 025 Generation
methoxylation of model compound (I) using porous polystyrene-supported and silica
gel supported piperidine piperazine affords the desired product in good to excellent
yields. Methanol is dissociated into methoxide anions and protons in the presence of
the solid-supported bases, and the resulting protons seem to be the main carrier of the
electronic charge. — (TAJIMA, T.; FUCHIGAMI*, T.; J. Am. Chem. Soc. 127 (2005)
9, 2848-2849; Dep. Electron. Chem., Tokyo Inst. Technol., Midori, Yokohama 226,
Japan; Eng.) — Klein
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