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2005
Oxidation
O 0212
31- 047
Palladium Nanoparticles Entrapped in Aluminum Hydroxide: Dual Catalyst for
Alkene Hydrogenation and Aerobic Alcohol Oxidation. — The catalyst is very effective in both hydrogenation of alkenes like cholesterol (I) or trans-chalcone (IV) and
aerobic oxidation of alcohols. Both catalytic processes can be successfully performed
in a one-pot manner. A variety of alcohols is oxidized whereby the process is more
effective in trifluoromethylbenzene than in toluene. The reaction is not effective for the
oxidation of primary aliphatic alcohols like (VIIIc). — (KWON, M. S.; KIM, N.;
PARK, C. M.; LEE, S. S.; KANG, K. Y.; PARK*, J.; Org. Lett. 7 (2005) 6, 1077-1079;
Div. Mol. Life Sci., Pohang Univ. Sci. Technol., Pohang 790-784, S. Korea; Eng.) —
R. Steudel
2005
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