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2005
Cyclopentane derivatives
Q 0030
A Neutral, Water-Soluble Olefin Metathesis Catalyst Based on an N-Heterocyclic
Ligand. — A poly(ethylene glycol) monomethyl ether is incorporated into a
31- 080 Carbene
ring closing metathesis catalyst. This product is easily soluble in water displaying greater activity in aqueous ring-opening metathesis polymerization than previously reported
water-soluble metathesis catalysts. Furthermore, the catalyst can be easily precipitated
from organic solvents with ether. — (GALLIVAN, J. P.; JORDAN, J. P.; GRUBBS*,
R. H.; Tetrahedron Lett. 46 (2005) 15, 2577-2580; Arnold and Mabel Beckman Lab.
Chem. Synth., Calif. Inst. Technol., Pasadena, CA 91125, USA; Eng.) — Mais
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