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2005
Hydrogenated naphthalene derivatives
Q 1010
Selective Allylic Hydroxylation of Octahydronaphthalene Derivatives with a
Double Bond Using Electrochemical Method with Iron Picolinate
31- 108 Bridgehead
Complexes. — Substrates with a bridgehead double bond like (I) give the allylic alcohol with α-preference, while the non-bridgehead olefin (V) does not react smoothly.
The presented electrochemical method is a useful tool for α-selective allylic hydroxylation of octahydronaphthalene derivatives with a bridgehead double bond as model
compounds for the AB fused ring of cholesterols. — (OKAMOTO, I.; FUNAKI, W.;
NOBUCHIKA, S.; SAWAMURA, M.; KOTANI, E.; TAKEYA*, T.; Chem. Pharm.
Bull. 53 (2005) 2, 248-252; Showa Pharm. Univ., Machida, Tokyo 194, Japan; Eng.)
— H. Haber
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