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2005
Amino acids
U 0400
Highly Functionalized Organolithium and Organoboron Reagents for the Preof Enantiomerically Pure α-Amino Acids. — A dianionic species is gener31- 166 paration
ated from Sem-protected, L-serine-derived chloro alcohol (I) and allowed to react with
a range of electrophiles. The novel boronic acid (IX) is available by the present method
and can be employed as a Suzuki cross-coupling partner elaborating a new pathway to
phenylalanine analogues like (XI). — (BARFOOT, C. W.; HARVEY, J. E.;
KENWORTHY, M. N.; KILBURN, J. P.; AHMED, M.; TAYLOR*, R. J. K.;
Tetrahedron 61 (2005) 13, 3403-3417; Dep. Chem., Univ. York, Heslington, York
YO10 5DD, UK; Eng.) — Klein
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