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2005
Silicon
I 0058
32- 019
Plasmachemistry, Formation of Chlorosilazanes, Chlorogermazanes and Related
Compounds. — The plasmachemically activated reaction between N2 and SiCl4 leads
to numerous chlorosilazanes: NSi3Cl 9, N 2Si 4Cl 10, NSi4Cl 11, N 2Si 4Cl 12, N2Si5Cl 14,
N3Si6Cl15 (3 isomers), N2Si6Cl 16 and some related compounds (NOSi4Cl11, N2O2Si6Cl14 ,
N2OSi5Cl 12). GeCl4 shows a similar behavior as shown by GC/MS. The structures of
N2Si5Cl14 , N2Si6Cl16 and N3Si 6Cl15 are determined by quantum chemical methods. —
(SCHIEFERHOEVEL, N.; HIMMEL, H.-J.; BINNEWIES*, M.; Z. Anorg. Allg.
Chem. 631 (2005) 8, 1507-1511; Inst. Anorg. Chem., Univ. Hannover, D-30167
Hannover, Germany; Eng.) — Schramke
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