close

Вход

Забыли?

вход по аккаунту

?

код для вставки
2005
Copper
I 7400
32- 034
A Unique Cyanide-Bridged Three-Dimensional (3-D) Copper(II)?Copper(I)
Mixed-Valence Polymer Containing 1-D Water Tapes with Cyclic Pentamer Units.
? The structure of the new mixed-valence polymer, {[Cu3(CN)4(H2O) 3](H 2O)2}n (III)
is determined by single crystal XRD (triclinic, space group P1, Z = 2). The compound
exhibits a unique three-dimensional zeolite-like coordination network in which CuI and
CuII centers are linked via CN bridges with (�?2) and (�?2) bridging modes. The
guest water molecules located in this net are trapped by H2O?H2O interactions with
the water ligands coordinated to CuII forming hydrogen-bonded water chains consisting
of linked cyclic water pentamers. ? (ZHENG*, J.-M.; BATTEN, S. R.; DU, M.;
Inorg. Chem. 44 (2005) 10, 3371-3373; Dep. Chem., Nankai Univ., Tianjin 300071,
Peop. Rep. China; Eng.) ? Schramke
Документ
Категория
Без категории
Просмотров
0
Размер файла
14 Кб
Теги
1/--страниц
Пожаловаться на содержимое документа