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2005
Hydroxylamine derivatives
Q 0110
Hydroxylamines as Oxygen Atom Nucleophiles in Transition-Metal-Catalyzed
Substitution. — A mild and facile approach to O-allylated hydroxylamines is
32- 086 Allylic
reported. In the presence of Ir2Cl2(cod)2 branched products are formed selectively,
whereas under Pd-catalysis linear products are obtained. The allylation proceeds with
good regio- and enantioselectivity using chiral ligands. — (MIYABE, H.; YOSHIDA,
K.; YAMAUCHI, M.; TAKEMOTO*, Y.; J. Org. Chem. 70 (2005) 6, 2148-2153;
Grad. Sch. Pharm. Sci., Kyoto Univ., Sakyo, Kyoto 606, Japan; Eng.) — Jannicke
2005
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