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2005
Hydrogenated naphthalene derivatives
Q 1010
The New Method for Introduction of an Allyl Group into the Angular Position
2-(TBS-Oxymethyl)-2,3,4,6,7,8-hexahydro-1-benzopyran-5-one and Its Appli32- 107 of
cation to Chiral Wieland—Miescher Type Compound Synthesis. — The synthetic
routes to the two diastereomeric Wieland-Miescher type compounds (X) and (XV) are
described. Key step is the stereoselective introduction of an allyl group into the angular
position of title compound (III) using Birch reduction and an enolate trapping reaction.
— (HIROYA*, K.; TAKAHASHI, T.; SHIMOMAE, K.; SAKAMOTO, T.; Chem.
Pharm. Bull. 53 (2005) 2, 207-213; Grad. Sch. Pharm. Sci., Tohoku Univ., Aoba,
Sendai 980, Japan; Eng.) — H. Haber
2005
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