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2005
Carbohydrates
U 0500
First Example of the Activation of Polymethylhydrosiloxane with Molecular
A Facile Synthesis of 3,6-Dihydropyran Derivatives. — Catalytic amounts
32- 179 Iodine:
of iodine are found to efficiently activate PMHS to provide a novel reactive combination for the conversion of glycals to 3,6-dihydropyrans. The system SiHEt3/I2 is also
found to be effective (no details given). — (YADAV*, J. S.; REDDY, B. V. S.;
PREMALATHA, K.; SWAMY, T.; Tetrahedron Lett. 46 (2005) 15, 2687-2690; Div.
Org. Chem., Indian Inst. Chem. Technol., Hyderabad 500 007, India; Eng.) — Mais
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