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2005
Structure
D 2000
33- 006
La3Cl 3BC — Structure, Bonding and Electrical Conductivity. — The title compound is prepared from a stoichiometric mixture of LaCl3, La, B, and C (1050 °C, 10 d).
La3Cl3BC crystallizes in the monoclinic space group P21/m with Z = 2 (single crystal
XRD). In the structure, monocapped trigonal prisms containing B—C units are condensed into chains along the b direction, and the chains are further linked by Cl atoms
in the a and c directions. Electrical conductivity measurements show that the compound
is metallic. — (ZENG, H.-Y.; OKUDERA, H.; ZHENG, C.; MATTAUSCH*, H.;
KREMER, R. K.; SIMON, A.; Z. Naturforsch., B: Chem. Sci. 60 (2005) 5, 499-504;
MPI Festkoerperforsch., D-70569 Stuttgart, Germany; Eng.) — W. Pewestorf
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