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2005
Thermal properties
D 3000
Exploring Thallium Compounds as Thermoelectric Materials: Seventeen New
Chalcogenides. — The new compounds Tl 2CeP2S7 (monoclinic, space
33- 008 Thallium
group P21/n), Tl3Ti2P5S18 (monoclinic, C2/c), Tl 2Cu 2SnS 4 (orthorhombic, Ibam),
Tl5AgTi6Se27 (trigonal, P31c), Tl3CuNb2Se12 (monoclinic, P21/n), Tl2M2SnTe4 (M: Cu,
Ag) (tetragonal, I42m), Tl3Zr1.4Sn1.6Te6 (rhombohedral, R3m),TlTiPS5 (triclinic, P1),
Tl2Au2Sn2Se6 (tetragonal, P4/ncc), TlLaGeSe4 (orthorhombic, Pbca), Tl2BiP2S7 (monoclinic, C2/c), Tl1.68NiTi2S5 (orthorhombic, Pnma), Tl2Cu2P2Se 6 (monoclinic, P21/n),
Tl2Au2P2Se6 (monoclinic, P2/m), TlInP2Se 6 (triclinic, P1), and
Tl11.5Sb 11.5Cu8Se27 (monoclinic, P2/m) are synthesized, their structures are determined,
and their thermoelectric properties (thermal conductivity, electrical resistivity, thermopower) are studied. All thermal conductivities are extremely low, however, most of
the materials are too resistive for thermoelectric applications. — (MCGUIRE, M. A.;
REYNOLDS, T. K.; DISALVO*, F. J.; Chem. Mater. 17 (2005) 11, 2875-2884; Dep.
Chem. Chem. Biol., Cornell Univ., Ithaca, NY 14853, USA; Eng.) — W. Pewestorf
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