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2005
Furan derivatives
R 0060
One-Pot Synthesis of Spirofuran and Benzocycloalka[1,2-b]furan Derivatives
Manganese(III)-Mediated Oxidative Radical Cyclization. — A convenient
33- 112 Using
one-pot synthesis of new functionalized spirofuran derivatives and title cycloalkafuran
derivatives via manganese(III)-mediated oxidative radical cyclization of methylenebenzocycloalkanes and/or-alkenes in the presence of 1,3-dicarbonyl compounds is
reported. The acid-catalyzed ring-opening reaction of some title compounds is also
described. — (FUJINO, R.; NISHINO*, H.; Synthesis 2005, 5, 731-740; Dep. Chem.,
Fac. Sci., Kumamoto Univ., Kurokami, Kumamoto 860, Japan; Eng.) — F. Santoso
2005
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