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2005
Quinoline derivatives
R 0410
Air-Stable Ir-(P-Phos) Complex for Highly Enantioselective Hydrogenation of
and Their Immobilization in Poly(ethyleneglycol) Dimethyl Ether
33- 156 Quinolines
(DMPEG). — An Ir-(P-Phos) catalyst is found to be highly effective in the asymmetric
hydrogenation of quinoline derivatives (I). The catalyst immobilized in polyethylene
glycol dimethyl ether can be recovered and reused several times, retaining reactivity
and enantioselectivity. — (XU, L.; LAM, K. H.; JI, J.; WU, J.; FAN, Q.-H.; LO, W.-H.;
CHAN*, A. S. C.; Chem. Commun. (Cambridge) 2005, 11, 1390-1392; Inst. Mol.
Technol Drug Discovery Synth., Hong Kong Polytech. Univ., Hong Kong, Kowloon,
Peop. Rep. China; Eng.) — M. Paetzel
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