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2005
Organo-silicon compounds
S 0060
Stereoselective Synthesis of α-Silylamines by the Direct Addition of Silyl Anions
Activated Imines. — The addition of silyl nucleophiles to activated imines under
33- 188 to
the conditions shown is a direct and highly stereoselective route to chiral α-silylamines.
The overall process is applicable to non-enolizable imines and various silyl anion structures. The products can be easily deprotected with high yields under acidic conditions.
— (BALLWEG, D. M.; MILLER, R. C.; GRAY, D. L.; SCHEIDT*, K. A.; Org. Lett.
7 (2005) 7, 1403-1406; Dep. Chem., Northwest. Univ., Evanston, IL 60208, USA;
Eng.) — R. Steudel
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