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2005
Alcohols
P 0110
34- 077
Enantio- and Diastereoselective Additions to Aldehydes Using the Bifunctional
Reagent 2-(Chloromethyl)-3-(tributylstannyl)propene: Application to a Synthesis
of the C16—C27 Segment of Bryostatin 1. — The coupling of aldehydes with the title
propene proceeds with high stereoselectivity. The resulting products are useful synthons which can smoothly be converted into interesting compounds such as the furan
derivative (VI) and the C16—C27 segment (XIV) of bryostatin 1. — (KECK*, G. E.;
YU, T.; MCLAWS, M. D.; J. Org. Chem. 70 (2005) 7, 2543-2550; Dep. Chem., Univ.
Utah, Salt Lake City, UT 84112, USA; Eng.) — Jannicke
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