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2005
Ethers
Q 0890
34- 129
The Cyclooligomerization of Arylethynes in Ionic Liquids Catalyzed by Ruthenium Porphyrins: A Case of Real Catalyst Recycling. — The cyclooligomerization
of arylethenes (I) and (IV) catalyzed by a Ru-porphyrin complex affords substituted
naphthalene derivatives (II)/(III) and (V), respectively, as major products. Only traces
of trisubstituted benzenes are found. Furthermore, the reaction can be performed in an
ionic liquid, which allows recycling of the catalyst and easy isolation of the products.
— (CONTE*, V.; ELAKKARI, E.; FLORIS, B.; MIRRUZZO, V.; TAGLIATESTA*,
P.; Chem. Commun. (Cambridge) 2005, 12, 1587-1588; Dip. Sci. Tecnol. Chim.,
Univ. Tor Vergata, I-00133 Roma, Italy; Eng.) — M. Paetzel
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