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2005
Bismuth
I 5400
35- 019
Anionic Diversity in Iodobismuthate Chemistry. — Three salts containing different
iodobismuthate anions are synthesized and their structures are determined by single
crystal XRD. Compound (II) crystallizes in the trigonal space group R3 with Z = 12
and contains monomeric [BiI6]3- octahedra. (IV) crystallizes in the monoclinic space
group C2/m with Z = 2 and contains edge-shared [Bi2I10]4- double-octahedra, while (V)
(triclinic, P1, Z = 2) contains face-shared [Bi2I9]3- double-octahedra. — (LINDSJOE,
M.; FISCHER, A.; KLOO*, L.; Z. Anorg. Allg. Chem. 631 (2005) 8, 1497-1501;
R. Inst. Technol., S-100 44 Stockholm, Swed.; Eng.) — Schramke
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