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2005
Cobalt
I 7200
35- 024
New Zeotype Borophosphates with Chiral Tetrahedral Topology:
(H)0.5M1.25(H2O)1.5[BP2O8]·H2O (M: Co(II) and Mn(II)). — The new borophosphates (II) crystallize in the hexagonal space group P6122 with Z = 1 (single crystal
XRD) and are isostructural with Fe(H2O) 2BP2O8·H2O. Their three-dimensional
open-framework structure is formed by ordered, alternating, corner-sharing BO4 tetrahedra, PO4 tetrahedra, and (MO4)OM(H 2O) 2 polyhedra. Magnetic susceptibility measurements indicate strong antiferromagnetic interaction between the metal centers in
both compounds. — (YILMAZ*, A.; YILDIRIM, L. T.; BU, X.; KIZILYALLI, M.;
STUCKY, G. D.; Cryst. Res. Technol. 40 (2005) 6, 579-585; Dep. Chem., Middle East
Tech. Univ., TR-06531 Ankara, Turk.; Eng.) — Schramke
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