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2005
Protection
O 0345
35- 060
The para-Siletanylbenzyl (PSB) Ether: A Peroxide-Cleavable Protecting Group
for Alcohols and Phenols. — Alcohol (IV) and bromide (V) are successfully employed for the preparation of protected phenols and primary alcohols. The Psb protecting group is easily removed under oxidative conditions. Its orthogonality with the
Pmb-group offers potential uses in multi-step synthesis. — (LAM, H.; HOUSE, S. E.;
DUDLEY*, G. B.; Tetrahedron Lett. 46 (2005) 19, 3283-3285; Dep. Chem.
Biochem., Fla. State Univ., Tallahassee, FL 32306, USA; Eng.) — Mais
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