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2005
Cyanic acid and cyanic acid derivatives
P 0520
Synthesis of Substituted 1-Thiocyanatobutadienes and Their Application in a
Sigmatropic Rearrangement Tandem Reaction. — A novel
35- 072 Diels—Alder/[3,3]
synthesis of enone (V) is described. The stereoselectivity of the enolization of (V) under
thermodynamically and kinetically controlled conditions is investigated with the aim
to synthesize 1(Z),2(E)-thiocyanato-butadienes (VII) and (IX). Compounds (VII) /(IX)
are planned to serve as intermediates in the synthesis of ibogamine. —
(LANASPEZE, S.; NEIER*, R.; Monatsh. Chem. 136 (2005) 4, 597-607; Inst. Chim.,
Univ. Neuchatel, CH-2000 Neuchatel, Switz.; Eng.) — M. Paetzel
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