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2005
Alcohols
Q 0230
35- 086
Polystyrenes with Chiral Phosphoramide Substituents as Lewis Base Catalysts for
Asymmetric Addition of Allyltrichlorosilane: Enhancement of Catalytic Performance by Polymer Effect. — In the asymmetric addition of allyltrichlorosilane (II) to
benzaldehyde (I), polystyrenes with chiral phosphoramide substituents as Lewis base
catalysts show significant better catalytic activity and higher enantioselectivity than the
corresponding low-molecular-weight analogues. — (OYAMA*, T.; YOSHIOKA, H.;
TOMOI, M.; Chem. Commun. (Cambridge) 2005, 14, 1857-1859; Dep. Mater.
Chem., Fac. Eng., Yokohama Natl. Univ., Hodogaya, Yokohama 240, Japan; Eng.) —
M. Paetzel
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