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2005
Thioethers
Q 0580
35- 100
Long Chain Phenols. Part 40. The Synthesis of Thiobisphenols from 3-Alkylphenols Derived from Natural Phenolic Lipids. — The reaction of 3-alkylphenols such
as 3-pentadecylphenol (I) with sulfur dichloride leads to the isomeric products (II) and
(III). These results are in contrast to previous work. The ratio (II)/(III) depends on the
solvent as well as on the catalyst used in the reaction. — (TYMAN*, J. H. P.;
JOHNSON, R. A.; J. Chem. Res. 2005, 2, 116-118; Dep. Chem., Brunel Univ.,
Uxbridge, Middlesex UB8 3PH, UK; Eng.) — H. Haber
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