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2005
Terpenes
U 0200
35- 208
Radical Cyclizations as Key Step for the Stereoselective Synthesis of Bi- and Tricyclic Sesquiterpene Lactones. — A feasible strategy that allows the diastereo- and
enantioselective construction of the title compounds is developed. The processes are
based on the enantioselective cyclopropanation of methyl 2-furoate and radical cyclization of appropriately substituted lactones (I), (III)/(IV), and (VII) under reaction conditions A). — (JEZEK, E.; SCHALL, A.; KREITMEIER, P.; REISER*, O.; Synlett
2005, 6, 915-918; Inst. Org. Chem., Univ. Regensburg, D-93053 Regensburg,
Germany; Eng.) — Mais
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