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2005
Polyphenylalkene derivatives
Q 0740
A Highly Stereoselective Preparation of CF3-Substituted 1-Aryl-1,2-diphenylApplication to the Synthesis of Panomifene. — A novel stereoselective
36- 078 ethenes:
synthesis of (E)-configured sulfone (Va) is described and its reaction with aryllithiums
is studied. In all cases completely stereoselective synthesis of triaryl olefins is observed. The process is utilized in a synthesis of panomifene (XII). — (KIM, M. S.;
JEONG*, I. H.; Tetrahedron Lett. 46 (2005) 20, 3545-3548; Dep. Chem., Yonsei
Univ., Wonju 220-710, S. Korea; Eng.) — Mais
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