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2005
Enantioselective syntheses
O 0031
2-(Aminomethyl)-oxazolines: Highly Modular Scaffolds for the Preparation of
Asymmetric Ligands. — A number of 2-(aminomethyl)-oxazoline-based de37- 026 Novel
rivatives such as (I)—(III) are prepared. Some of them are good ligands for the asymmetric addition of ZnEt2 to aldehydes. Best results are obtained with (Ic). However, the
reaction of ketones gives disappointing results. — (VAESTILAE, P.; PASTOR, I. M.;
ADOLFSSON*, H.; J. Org. Chem. 70 (2005) 8, 2921-2929; Dep. Org. Chem.,
Arrhenius Lab., Univ. Stockholm, S-106 91 Stockholm, Swed.; Eng.) — Jannicke
2005
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