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2005
Enantioselective syntheses
O 0031
A Recyclable Catalyst for Asymmetric Transfer Hydrogenation with a Formic
Mixture in Ionic Liquid. — A known modified arene-Ru(II)
37- 030 Acid—Triethylamine
complex with Noyori's chiral TosDPEN ligand and a novel catalytic Ru(II) system involving a task-specific ionic ligand having an imidazolium moiety prove to be recyclable and efficient catalysts for the asymmetric transfer hydrogenation of ketones (I) in
an ionic liquid. The new ionic catalyst system shows somewhat better results than the
known catalyst in the recyclable asymmetric transfer hydrogenation. —
(KAWASAKI, I.; TSUNODA, K.; TSUJI, T.; YAMAGUCHI, T.; SHIBUTA, H.;
UCHIDA, N.; YAMASHITA, M.; OHTA*, S.; Chem. Commun. (Cambridge) 2005,
16, 2134-2136; Dep. Funct. Mol. Chem., Kyoto Pharm. Univ., Yamashina, Kyoto 607,
Japan; Eng.) — R. Staver
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