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2005
Furan derivatives
R 0060
Palladium-Catalyzed Synthesis of Tetrahydrofurans from γ-Hydroxy Terminal
Scope, Limitations, and Stereoselectivity. — The title reaction offers a new
37- 102 Alkenes:
and useful method for the stereoselective formation of a wide variety of substituted
tetrahydrofurans, including spirocyclic and bicyclic derivatives. The yield is dependent
on steric and electronic effects. In some cases, a synthesis of the target compounds is
not successful. Starting from tertiary alkenols and 3-substituted 4-pentenols steric and
electronic factors also affect the stereochemical outcome. — (HAY, M. B.; HARDIN,
A. R.; WOLFE*, J. P.; J. Org. Chem. 70 (2005) 8, 3099-3107; Dep. Chem., Univ.
Mich., Ann Arbor, MI 48109, USA; Eng.) — Jannicke
2005
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